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Polymer Sciences | ISSN: 2471-9935

October 02-03, 2017 Chicago, USA

3

rd

International Conference on

Polymer Science and Engineering

Thermo-mechanical characterizations of polymers for microelectronics applications

Kossi Nicolas Assigbe

1,2

, Lionel Vignoud

1

, Guillaume Parry

2

and

Rafael Estevez

2

1

University of Grenoble Alpes, CEA, LETI, Minatec Campus, France

2

University of Grenoble Alpes, CNRS, France

I

n microelectronics, 3D integration involves stacking different electronic components on a substrate. During the various steps of the

process, bonding is carried out using several types of polymeric materials. The use of these materials can be advantageous: they are

generally carried out at deposition temperatures lower than those of the other integrated materials and it is possible to integrate them

in liquid form under components and then crosslink them. They also have the advantage of offering various mechanical properties,

which make it possible both to protect certain components but also to produce more flexible layers if necessary. Conversely, they

exhibit high coefficients of thermal expansion (CTE), which can lead to problems of reliability of the components. Moreover, their

mechanical properties can change over time when the crosslinking annealing has not been optimized. Thus, their characteristics

may be unstable when used in manufacturing processes. The aim of this work is to develop a method for studying the evolution of

thermomechanical properties of polymers used in manufacturing processes as a function of temperature. In the first part of this work

we carried out experimental measurements using a measuring equipment (k-SA MOS Thermoscan) to measure the evolution of the

curvature of deposit materials on substrate. We carried out this study for different types of polymer materials deposited on a silicon

substrate. The objective is to measure their curvature evolution for different temperature. The equipment is equipped with an in-situ

furnace which allows us to heat the plate with a controlled temperature ramp from ambient temperature up to 1000 ° C. In the second

part we have developed an analytical calculation program to solve static equilibrium equations during cooling or heat treatment

taking into account thermo-elastic properties variation. From the measurements of curvature variations, an inverse analysis makes it

possible to identify the thermo elastic properties of the polymers films. Finite element validation will also be presented.

Biography

Kossi Nicolas ASSIGBE, I am a young researcher of 24 years born in TOGO with a diploma of mechanical design engineer (TOGO, 2014) and a master research in ma-

terials mechanics (France, 2015). Passionate about understanding the behavior of materials, I am now working on the temperature instability of the thermomechanical

properties of polymer films used in microelectronics. I am a PhD student based at CEA (Commissariat of Atomic Energy and Alternative Energies) and SIMaP (Laboratory

of Science and Engineering of Materials and Processes).

Kossinicolas.ASSIGBE@cea.fr

Kossi Nicolas Assigbe et al., Polym Sci, 3:3

DOI: 10.4172/2471-9935-C1-002