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Organic Chemistry 2018 Journal of Organic & Inorganic Chemistry
ISSN: 2472-1123 Page 49
August 16-17, 2018
Dublin, Ireland
6th Edition of International
Conference and Exhibition on
Organic Chemistry
N-heterocycliccarbenes (NHCs) areknown toformcoordination
complexes with transition metals, also their coordination
chemistry with main group elements is well established. In the
recent past, thenitrogencationcentrewasproven tobeanefficient
electron accepting centre. The unique bonding nature of electron
donating ligands (NHC/Carbocyclic carbene) and nitrogen cation
centre inspired us to design several complexes having (L→N←L′)+
species and explore their applicability. In this work, the quantum
chemical design, synthesis and X-ray diffraction analysis of the
same are presented. Quantum chemical analysis established
the divalent NI character at the central nitrogen, X-ray diffraction
studies validated the structural features.
C→N coordination bonds in (NL2)+ complexes
Neha Patel
NIPER, India
J Org Inorg Chem 2018, Volume 4
DOI: 10.21767/2472-1123-C4-012