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NanoMat 2018

Nano Research & Applications

ISSN: 2471-9838

Page 49

April 26-27, 2018

Rome, Italy

17

th

Edition of International Conference on

Emerging Trends in

Materials Science and

Nanotechnology

T

he last decade of past century was marked by a revolution

in the field of materials synthesis for optical and photonic

applications. It is noteworthy that major dispute regarding

the origin of these materials: inorganic or organic, natural or

synthetic, hybrid or pure? The goal of our work is that attempting

to obtain a controlled structure and then improving the properties

by adding small amounts of DNA or chromophores. The idea

for using these partners is to get desired applications which

regard the biophotonic / nonlinear optical (NLO) field. The used

chromophores were synthesized starting from NLO sequences

and contains both azo-benzenes and carbazole groups in order

to induce a response to an external and/or internal stimulus.

DNA is also used in NLO application but has another important

property and that is targeting specific molecules/cells/tissues.

This study was made to understand the perfect combination

between the monomers (amides) and DNA/chromophores. The

importance of this work is to highlight the best conditions and

the mechanism to obtain new polymers with induced properties

in order to be applied in specific fields. Moreover, we have a

shot to prove the structure and properties control by reaction

parameters. Themolecular interaction and the surroundingmedia

play an important role in changing of the fundamental properties

of materials. So the electronically behaviors at molecular level are

principallydeterminedby theconcentrationof theNLOconstitutive

sequences. Demonstrating how such materials respond to a

sensitive stimulus which affects the polar ordering is given by

the solvatochromic, VCD, FT-IR and Raman studies. The physical

- chemical characterization of novel compounds, proposed by us,

foreshadows the potential applications of polymer materials, with

such sequences, in the biophotonic and NLO field.

Recent Publications

1. J B Lee, A S Shai, M J Campolongo, N Park and D

Luo (2010) Three-dimensional structure and thermal

stability studies of DNA nanostructures by energy

transfer spectroscopy. ChemPhysChem 11: 2081-

2084.

2. A Rodriguez-Pulido, A I Kondrachuk, D K Prusty, J

Gao, M A Loi and A Herrmann (2013) Light-Triggered

Sequence-Specific Cargo Release from DNA Block

Copolymer–Lipid Vesicles. Angewandte Chemie

International Edition 52:1008-1012.

3. R M Zadegan and M L Norton (2012) Structural

DNA nanotechnology: from design to applications.

International Journal of Molecular Sciences 13:7149-

7162

4. A Czogalla, H G Franquelim and P Schwille (2016) DNA

nanostructures on membranes as tools for synthetic

biology. Biophysical Journal 110:1698-1704.

5. Aldea, A M Albu and I Rau (2016) New polymeric

materials for photonic applications: Preliminary

investigations. Optical Materials 56:90-93.

Biography

Ana Maria Albu has her expertise in the field of Polymer Science and related

fields such as: organic synthesis, smart materials, design and manufacture

of the new architecture materials with peculiar applications like optic, op-

to-electronic, micro-electronics, photonic; biomaterials. Two main directions

are distinguished: particular aspects in macromolecular synthesis and syn-

thesis of polymeric materials with non-conventional applications. For her,

the research activity is closely related to didactic activity, her being devot-

ed teacher to training and orientation of students to specialized technical

domains. It is a recognized presence in the field’s conferences through the

interdisciplinary approach of its research. In recent years, she has focused

her activity to the synthesis and characterization of polymer materials with

applicability in the biophotonic field. At the same time, by interdisciplinary

approaches, it is looking for solution for novel, eco-friendly polymer mate-

rials with applications in the field of fuel cells, selective recovery of metallic

ions, specialized coating.

anamarialbu@yahoo.com

Structural peculiarities of the polymer-DNA assembles

Ana Maria Albu

Politehnica University of Bucharest, Romania

Ana Maria Albu et al., Nano Res Appl, Volume:4

DOI: 10.21767/2471-9838-C1-008

Figure 1:

The chemical structures of the mainmaterials used

to make polymer-DNA Assembles.