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E u r o S c i C o n C o n f e r e n c e o n

Chemistry

2018

Chemistry 2018

Journal of Organic & Inorganic Chemistry

ISSN 2472-1123

F e b r u a r y 1 9 - 2 0 , 2 0 1 8

P a r i s , F r a n c e

Page 38

Z

eolite synthesis out of fly ash is a worth noticing, low budget alternative

for the production of zeolites compared to natural zeolites or zeolites

produced from pure chemicals. Generally, zeolites due to their structure

represent interesting properties (ion-exchange, catalytic, sorptive). Based

on the sorption properties it is possible to use this material as a sorbent

for flue gases impurities such as carbon dioxide. Energy sector in Poland is

mainly based on burning of brown and hard coal. Environmental concerns

and legal aims oblige to reduce the emission of greenhouse gases emitted

to the atmosphere. Due to restrictions on the emission limits, it is crucial to

search for differentiated methods for CO

2

capturing adapted for the economy

new needs. The use of zeolites such as sorbent in the industrial processes

may have a positive ecological result, not only due to the elimination of

disadvantages of commonly used CO

2

capture absorption methods, but also

due to the usage of waste material as a raw material for the synthesis. Fly

ash zeolites may be synthesised by different methods which affect the final

product. It influences the type and amount of zeolite present in the synthesized

sample and in this way the sorption properties of synthesized materials. In this

work, the comparison of CO

2

sorption of 3 fly ash zeolites samples synthesized

by differentiated methods were presented. Synthesis methods chosen were:

hydrothermal method, fusion method and modified two-step method. Results

indicated different sorption capacity due to zeolite type present, synthesis

efficiency and for similarities in isotherm shapes connected with the presence

of micropores.

Biography

N Czuma is a PhD student at AGH University of Science and

Technology in Kraków, Poland. Her PhDwork focuses on fly ash

synthesis and its sorption properties in relation to CO2 and SO2.

Additionally, her scientific interest focuses on other fly ash uses

such as carbonation processes and geopolymer synthesis. She

is a member of InnoEnergy PhD School. She had participated

in national and international internships including cooperation

with EDF Poland S A, Lublin University of Technology, UPC-Uni-

versitat Polytecnica de Catalunya and Université Pierre et Marie

CURIE.

nczuma@agh.edu.pl

Carbon dioxide sorption properties of fly ash zeolites differentiated in

case of synthesis process

N Czuma, K Szczurowski, K Zarębska and P Baran

AGH University of Science and Technology, Poland

N Czuma, J Org Inorg Chem 2018, Volume: 4

DOI: 10.21767/2472-1123-C1-002