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Volume 3, Issue 2 (Suppl)
Trends in Green chem
ISSN: 2471-9889
Environmental & Green Chemistry 2017
July 24-26, 2017
Page 36
5
th
International Conference on
6
th
International Conference on
July 24-26, 2017 Rome, Italy
Environmental Chemistry and Engineering
Green Chemistry and Technology
&
Dosing of proper oxidizing agents pretreatment to Kalatuwawa water to reduce the Trihalomethane
(THM) formation in drinking water
Jayalal L P R Wijesinghe, Nishantha D P Welikala, K P R S Samarasinghe
and
Ranjith C Perera
National Water Supply and Drainage Board, Sri Lanka
K
alatuwawa water treatment plant consists of aeration, coagulation, flocculation, sedimentation, filtration and disinfection.
Existing aeration is not enough to oxidize the inorganic and organic impurities in Kalatuwawa raw water, therefore prechlorine
is used as oxidizing agent in Kalatuwawa. Analytical results revealed that during the years 2000–2012, the Kalatuwawa raw water
contained high concentration of ammonia (0.578±0.469 mg/dm
3
), and highest concentration of ammonia 1.92 mg/dm3 was reported
at the bottom of the reservoir, high concentration of iron (0.751±0.643 mg/dm
3
), and the highest concentration of iron 12 mg/dm
3
was reported at the bottom of the reservoir. The color levels were 11.571±7.271 Hz and the highest level of color, 90 Hz was reported
at the bottom of the reservoir. Pre chlorination where chlorine is utilized not only oxidize the iron, manganese, ammonia and organic
compounds but also reacts with naturally occurring organic matter present in water to produce a group of organic compounds as a
byproduct arising from chlorination which was classified as Trihalomethane (THM). THMs are often used as indicator compounds
for other DBPs. The four main THM compounds found in abundance are chloroform (CHCl
3
), bromodichloromethane (CHCl
2
Br),
dibromochloromethane (CHClBr
2
) and bromoform (CHBr
3
). Many factors which will affect the THM formation are concentration
and type of precursors, type of disinfectant and concentration and the dosing point, temperature, pH, contact time and the length of the
distribution network. This study is basically investigating THM formation without prechlorination where potassium permanganate
(KMnO
4
) is used as pretreatment to remove the organic and inorganic impurities. Laboratory analysis was carried out using Jar test
apparatus with potassium permanganate to remove the impurities. Analytical results revealed that 90% of iron was removed with
0.3-0.6 mgdm-3 dosage of potassium permanganate and the same time manganese level is within SLS 614: 2013. THM levels were
monitored using GC–ECD couple to purge and trap system where the THM levels were reduced significantly (67%).
Biography
Jayalal L P R Wijesinghe graduated from University of Colombo, Sri Lanka with a BSc (Hons) degree. After graduation, he has joined the Department of Chemistry,
University of Colombo as a Demonstrator then as a Researcher. He has obtained PG Diploma in the field of Toxicology and MSc degree in the field of Analytical
Chemistry from the same university. He has started his water sector career as a Regional Chemist attached to the National Water Supply & Drainage Board in North
Central Province of Sri Lanka. After successful completion of eight years of regional works, he was promoted to the Senior Chemist position in NWSDB. Presently
he is working as a Chief Chemist in NWS&DB in Sri Lanka. He has gained 22 years of experience in the field of Water Quality Monitoring with the operation of high
end analytical instruments – AAS with GTA, GC/MS, etc. He has published twelve research papers in local and international journals. He has undergone many
training programs locally as well as internationally like – Lake Water Quality Management course in Japan, LC/MS training course at Waters in India, Analytical
Skills Development Course in Helsinky University in Finland, etc. He is a Fellow Member of the Institute of Chemistry, Ceylon and also a Chartered Chemist.
lprjw@yahoo.comJayalal L P R Wijesinghe et al., Trends in Green chem, 3:2
DOI: 10.21767/2471-9889-C1-002