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Journal of Organic & Inorganic Chemistry
ISSN 2472-1123
2
n d
E d i t i o n o f E u r o S c i C o n C o n f e r e n c e o n
Chemistry
F e b r u a r y 1 9 - 2 0 , 2 0 1 9
P r a g u e , C z e c h R e p u b l i c
Chemistry 2019
T
he stereoselective addition of reagents containing the chiral 10-substituted-9-borabicyclo[3.3.2]decane (BBD) moiety
to aldehydes, ketones, aldimines and ketimines will be described. The rigid and robust nature of these systems permits a
wide variety of organoborane conversions to not only be conducted in a highly enantioselective manner, but also, it facilitates
the recovery of the chiral borane by-product which can be recycled through simple operations. Moreover, numerous chemical
conversions can be performed on these organoboranes providing remarkable new reagents for organic synthesis. The origin of
the observed selectivities will be presented and discussed in terms of the compact chiral reaction centers provided by the BBD
systems.
jasoderquist@yahoo.comAsymmetric organoborane conversions via the
amazing 9-borabicyclo[3.3.2]decanes
John A Soderquist
University of Puerto Rico, USA
J Org Inorg Chem 2019, Volume: 5
DOI: 10.21767/2472-1123-C1-021