Journal of Organic & Inorganic Chemistry

C-N coordination bonds in (NL2)+ complexes

6^th Edition of International Conference and Exhibition on Organic Chemistry
August 16-17, 2018 Dublin, Ireland

Neha Patel

NIPER, India

Posters & Accepted Abstracts: J Org Inorg Chem

DOI: 10.21767/2472-1123-C4-012

Abstract

N-heterocyclic carbenes (NHCs) are known to form coordination complexes with transition metals, also their coordination chemistry with main group elements is well established. In the recent past, the nitrogen cation centre was proven to be an efficient electron accepting centre. The unique bonding nature of electron donating ligands (NHC/Carbocyclic carbene) and nitrogen cation centre inspired us to design several complexes having (L→N←L′)+ species and explore their applicability. In this work, the quantum chemical design, synthesis and X-ray diffraction analysis of the same are presented. Quantum chemical analysis established the divalent NI character at the central nitrogen, X-ray diffraction studies validated the structural features.

Biography

E-mail:

nehapateldops@gmail.com