Structural and conformational studies of 2,4-diphenyl-3- azabicyclo[3.3.1]nonan-9-one-o-nicotinoyloxime

The title compound crystallizes with the monoclinic cell setting and P2(1)/n space group. The structural compound C26H25N3O2 exist in a twin-chair conformation with equatorial orientation of the phenyl group. The two phenyl rings attached to the piperidine ring at positions 2 and 4 have equatorial orientation. The angle between the two benzene rings is 48.32(9)°. The crystal structure is further stabilized by C-H...N, C-H...\pi and intramolecular interaction.

Author(s): T. Mohandas, K. Gokula Krishnan, V. Thanikachalam and P. Sakthivel

Abstract | PDF

Share This Article